Томашик, В. М., Shcherbak, L. P., Feichuk, P. I., Гриців, В. І.
(2006)
Crystallization Features of Ternary Reversible Reciprocal Systems.
Russian Journal of Inorganic Chemistry, 51 (3).
pp. 465-469.
ISSN 0036-0236
Abstract
Some features of the primary crystallization of phases in ternary reversible reciprocal system are considered and discussed. The diagonal join CdTe–GeSe of the CdTe + GeSe CdSe + GeTe ternary reciprocal system is studied to show that the features in primary and secondary heating and cooling curves in such systems under fully equilibrium conditions are not reproduced upon consecutive heating and cooling sessions,
because of the existence of different amounts of the reagents and the reaction products in the mixture; the temperatures of each transformation lie in a range. Those who experimentally investigate other ternary and more
complex reversible reciprocal systems should take this fact into account.
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